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Determination of the Aspect-ratio Distribution of Gold Nanorods in a Colloidal Solution using UV-visible absorption spectroscopy

Kumar, R., Binetti, L., Nguyen, H. T., Alwis, L. S. M., Agrawal, A., Sun, T. ORCID: 0000-0003-3861-8933 and Grattan, K. T. V. ORCID: 0000-0003-2250-3832 (2019). Determination of the Aspect-ratio Distribution of Gold Nanorods in a Colloidal Solution using UV-visible absorption spectroscopy. Scientific Reports, 17469.. doi: 10.1038/s41598-019-53621-4

Abstract

Knowledge of the distribution of the aspect ratios (ARs) in a chemically-synthesized colloidal solution of Gold Nano Rods (GNRs) is an important measure in determining the quality of synthesis, and consequently the performance of the GNRs generated for various applications. In this work, an algorithm has been developed based on the Bellman Principle of Optimality to readily determine the AR distribution of synthesized GNRs in colloidal solutions. This is achieved by theoretically fitting the longitudinal plasmon resonance of GNRs obtained by UV-visible spectroscopy. The AR distribution obtained from the use of the algorithm developed have shown good agreement with those theoretically generated one as well as with the previously reported results. After bench-marking, the algorithm has been applied to determine the mean and standard deviation of the AR distribution of two GNRs solutions synthesized and examined in this work. The comparison with experimentally derived results from the use of expensive Transmission Electron Microscopic images and Dynamic Light Scattering technique shows that the algorithm developed offers a fast and thus potentially cost-effective solution to determine the quality of the synthesized GNRs specifically needed for many potential applications for the advanced sensor systems.

Publication Type: Article
Additional Information: © The Author(s) 2019. This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Cre-ative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not per-mitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
Subjects: T Technology > TK Electrical engineering. Electronics Nuclear engineering
Departments: School of Mathematics, Computer Science & Engineering > Engineering > Electrical & Electronic Engineering
Date Deposited: 04 Nov 2019 17:12
URI: https://openaccess.city.ac.uk/id/eprint/23153
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