Turning Trash into Treasure: Silicon Carbide Nanoparticles from Coal Gangue and High-Carbon Waste Materials
Gao, K., Zhang, Y., Wang, B. , Zhang, Z., Luo, S., Wang, Q., Zhen, Y., Fu, F. 
ORCID: 0000-0002-9176-8159 & Liang, Y. (2025).
Turning Trash into Treasure: Silicon Carbide Nanoparticles from Coal Gangue and High-Carbon Waste Materials.
Molecules, 30(7),
article number 1562.
doi: 10.3390/molecules30071562
Abstract
To reduce solid waste production and enable the synergistic conversion of solid waste into high-value-added products, we introduce a novel, sustainable, and ecofriendly method. We fabricate nanofiber and nanosheet silicon carbides (SiC) through a carbothermal reduction process. Here, the calcined coal gangue, converted from coal gangue, serves as the silicon source. The carbon sources are the carbonized waste tire residue from waste tires and the pre-treated kerosene co-refining residue. The difference in carbon source results in the alteration of the morphology of the SiC obtained. By optimizing the reaction temperature, time, and mass ratio, the purity of the as-made SiC products with nanofiber-like and nanosheet-like shapes can reach 98%. Based on the influence of synthetic conditions and the results calculated from the change in the Gibbs free energy of the reactions, two mechanisms for SiC formation are proposed, namely the reaction of intermediate SiO with CO to form SiC-nuclei-driven nanofibrous SiC and the SiO-deposited carbon surface to fabricate nuclei-induced polymorphic SiC (dominant nanosheets). This work provides a constructive strategy for preparing nanostructured SiC, thereby achieving “turning trash into treasure” and broadening the sustainable utilization and development of solid wastes.
| Publication Type: | Article |
|---|---|
| Additional Information: | © 2025 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
| Publisher Keywords: | re-utilization of waste resources, turning trash into treasure, nanostructured silicon carbide, morphological control, carbothermal reduction reaction |
| Subjects: | T Technology > TA Engineering (General). Civil engineering (General) |
| Departments: | School of Science & Technology School of Science & Technology > Department of Engineering |
| SWORD Depositor: |
Available under License Creative Commons Attribution.
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